MADB Publication Report



PUBLICATION

Publication Title  Electrode reaction of the Np3+/Np couple at liquid Cd and Bi electrodes in LiCl - KCl eutectic melts 
Journal/Book  Journal of Applied Electrochemistry 
Publisher  Kluwer Academic Publishers 
Type  Periodical 
Volume  34 
Year  2004 
Pages  323 - 330 
Web Address   

AUTHORS

Author Author's Institute when publication was made
O. Shirai  Japan Atomic Energy Research Institute (JAERI) 
K. UOZUMI   
T. Iwai  Japan Atomic Energy Agency (JAEA) 
Y. Arai  Japan Atomic Energy Agency (JAEA) 

PUBLISHED DATA

No  Caption Data
1:  Free energy of formation  of  NpBi2  
2:  Free energy of formation  of  NpCd11  
3:  Free energy of formation  of  NpCd6  
4:  Redox potential  of  Np3+/Np  
5:  Redox potential  of  Np3+/Np  
Data presented in Table: Cathodic and anodic peak potentials, Ecp and Eap , and cathodic half-peak potential in the cyclic voltammograms for the redox reaction of the Np3+/Np couple at liquid Cd elect   
6:  Redox potential  of  Np3+/Np-Bi  
Er [Np3+/Np-Bi] = -1.092 V    (T = 723 K)
Er [Np3+/Np-Bi] = -1.066 V    (T = 773 K)
Er [Np3+/Np-Bi] = -1.037 V    (T = 823 K)
7:  Redox potential  of  Np3+/Np-Cd  
Er [Np3+/Np-Cd] = -1.361 V    (T = 723 K)
Er [Np3+/Np-Cd] = -1.345 V    (T = 773 K)
Er [Np3+/Np-Cd] = -1.321 V    (T = 823 K)
     

Previous   (Electrochemical Oxidation of Am(V) Ions in HNO3 Solutions) (Electrolytic reduction of spent oxide fuel in a molten LiCl-Li2O system)   Next